“The 1831 eruption of Babuyan Claro in the Philippines is regarded as one of the most significant volcanic climate forcing events of the nineteenth century, particularly so when treated as a double eruption with the 1835 (VEI 5) eruption of Cosegüina, producing ‘enhanced’ forcing effects over a decadal time frame.”
Follows the course of much detective work and its conclusion:
“We therefore suggest that the 1831 eruption of Babuyan Claro is a false event and that one or more alternative eruptions will have to be identified as the source of the 1831 stratospheric sulphate aerosol.” Continue Reading
Philippines
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Mayon in eruption Jan 23. Photo courtesy Philstar Global. http://www.philstar.com/headlines/2018/01/24/1780930/mayon-volcano-spreads-lava-3-kilometers-crater

Pinatubo in Eruption June 1991 – http://bigthink.com/eruptions/why-volcanism-isnt-the-source-of-increasing-carbon-dioxide-emissions